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Counterintuitive design principles for tuning metal-centered excited states in Co(III) polypyridine complexes are reported by Wenger et al. in the Journal of the American Chemical Society from ACS Publications (🔎 https://ccdc-info.com/4mTzfeG). By optimizing ligand bite angles and leveraging π-π interactions, they achieved longer-lived excited states despite weaker ligand fields—a stark contrast to traditional transition metal complexes. CSD Entry SAHWAE shows π-π interactions between quinoline
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